
Polarisation in a simple cell
ZIMSEC O Level Combined Science Notes: Perfecting the electric cell
Voltage/Potential difference
- The voltage between the two electrodes is dependent on the type of electrode used
 - When magnesium and copper are used the potential difference between the two electrodes is fairly high
 - Enough current flows to even light a bulb
 - If copper and zinc are used the voltage is insufficient to light the lamp
 - The current can however be read on an ammeter
 - A voltmeter can also be used to measure the voltage of the cell
 - It will show that the magnesium-zinc battery produces a higher voltage and more current than a copper-zinc cell
 
| Negative Terminal | Positive Terminal | 
|---|---|
| Magnesium | Copper | 
| Zinc | Lead | 
| Iron | Iron | 
| Lead | Zinc | 
| Copper | Magnesium | 
- The table above shows the metals which could be used to make an electric cell
 - The least reactive metal can be used to make the positive terminal
 - The most reactive metal will be used to make the negative terminal
 - The further apart the minerals in the series the greater the potential difference (voltage)
 - For example the Magnesium-Copper cell gives the most potential difference
 - The Lead copper cell would give the least potential difference
 - A simple with a zinc plate for an electrode and
 - A copper plate for an electrode
 - and dilute sulphuric acid as an electrolyte
 - produces about 1 volt
 
Polarisation
- After only a short time the cell stops working due to polarisation
 - Polarisation-this is when hydrogen bubbles collect on the copper plate of a simple electric cell and act as an insulator
 - Polarisation can be overcome by wiping the bubble off the plate at intervals
 - It can also be solved by adding a depolirising agent
 - A little potassium manganate (VII) to oxidise the hydrogen as soon as it forms
 
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